Thorium uranium dating
Lava erupting earlier would come from the top of the magma chamber, and lava erupting later would come from lower down.
A number of processes could cause the parent substance to be depleted at the top of the magma chamber, or the daughter product to be enriched, both of which would cause the lava erupting earlier to appear very old according to radiometric dating, and lava erupting later to appear younger.
55-57, (1987), gives us an idea of the tremendous complexity of the processes that occur when magma solidifies.
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As the crystallization process continues, the composition of the melt (liquid portion of a magma, excluding any solid material continually changes.
For example, at the stage when about 50 percent of the magma has solidified, the melt will be greatly depleted in iron, magnesium, and calcium, because these elements are found in the earliest formed minerals.